Chemistry and Chemical Biology ETDs
Publication Date
5-4-1977
Abstract
The photolyses of a series of chromium(III) complexes Cr(en)3 3+, Cr(den)2 3+, Cr(tn)3 3+, and Cr(pn)3 3+, where en= ethylenediamine, den= diethylenetriamine, tn = trimethylenediamine, and pn = propylenediamine, have been investigated. Experiments were carried out on unbuffered and buffered (pH= 2.00) solutions containing 10^-3 – 10^-2 M chromium(III) complexes at room temperature and 10°C. While purging with argon or oxygen, the irradiation was performed with 184.9-253.7 nm u.v. light, corresponding to the charge transfer bands of the complex.
Language
English
Document Type
Dissertation
Degree Name
Chemistry
Level of Degree
Doctoral
Department Name
Department of Chemistry and Chemical Biology
First Committee Member (Chair)
William Fletcher Coleman
Second Committee Member
Robert Edwin Tapscott
Third Committee Member
Fritz Schreyer Allen
Recommended Citation
Kang, Yohn Sik. "Charge Transfer Photochemistry Of Some Chromium (Iii) Complexes." (1977). https://digitalrepository.unm.edu/chem_etds/262
Comments
University of New Mexico financial aid. Sandia Corporation research assistamtship