Civil Engineering ETDs
Publication Date
Summer 6-5-2017
Abstract
Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. This work evaluates the implementation of the common chemical coagulant ferric chloride (FeCl3) and highly insoluble ferric hydroxide (Fe(OH)3) in the removal of silica by coagulation and adsorption mechanisms, respectively. Ferric chloride was optimized for silica colloid coagulation in IC wastewater via charge neutralization resulting in 97.2% turbidity removal. Adsorption of reactive silica on ferric hydroxide using a sequencing batch reactor approach exhibited 94.6% silica removal for the first adsorption cycle in under 60 minutes. Silica adsorption was found to fit the Langmuir isotherm relationship and was further modeled with surface complexation reactions using PHREEQC. Analytical characterization provided evidence of silica polymerization on the iron surface. This work serves to provide a benchmark of ferric chloride and ferric hydroxide application in silica removal for real industrial wastewater streams. Marrying these compounds together has proven to be an effective approach for comprehensive silica removal.
Keywords
water reuse, silica, coagulation, adsorption, IC, RO
Sponsors
National Science Foundation CREST and EAPSI programs
Document Type
Thesis
Language
English
Degree Name
Civil Engineering
Level of Degree
Masters
Department Name
Civil Engineering
First Committee Member (Chair)
Dr. Kerry J. Howe
Second Committee Member
Dr. Patrick V. Brady
Third Committee Member
Dr. Jr-Lin Lin
Recommended Citation
Baca, Ehren D.. "Comprehensive Silica Removal with Ferric Compounds for Industrial Wastewater Reuse." (2017). https://digitalrepository.unm.edu/ce_etds/176
Included in
Civil Engineering Commons, Environmental Chemistry Commons, Environmental Engineering Commons, Environmental Health and Protection Commons, Geochemistry Commons, Inorganic Chemistry Commons, Natural Resources and Conservation Commons, Oil, Gas, and Energy Commons, Other Environmental Sciences Commons, Sustainability Commons, Water Resource Management Commons