Chemical and Biological Engineering ETDs
Publication Date
Winter 12-12-2020
Abstract
Through-silicon vias (TSVs) are a key interconnect technology for advanced packaging of microelectronic devices, and full wafer thickness TSVs are required for certain microelectromechanical systems (MEMS) applications. In this work, electrolytes containing copper sulfate, an acid, chloride, and Tetronic 701 suppressor were implemented for Cu filling of high aspect ratio (10:1), full wafer thickness TSVs. For each electrolyte system, rotating disk electrode voltammetry was used to identify a voltage range for bottom-up Cu filling in the TSVs. Die level feature filling was performed using voltage ramping, which moved active deposition through the vias to yield void-free Cu features. During voltage-controlled deposition experiments, current was measured, and a characteristic current minimum was identified, which is presented as a process endpoint detection method for TSV Cu filling.
To transition these Cu plating processes from the die to wafer level, experiments were performed to identify parameters required for wafer level plating. Since wafer level electroplating tools often do not have reference electrodes, a current-controlled deposition method was developed at the die level. To scale the deposition process from small 1 cm2 samples to a full wafer, multi-die scaling experiments were performed to evaluate how current scales with active plating area. Since vias along a rotating wafer’s radius have different linear velocities, rotation rate studies were conducted to observe the relationship between fluid flow and Cu fill profile. Future work will transition these results to a wafer level plating capability to produce full wafer thickness Cu-filled TSVs for MEMS and other microelectronics applications.
Keywords
TSVs, through-silicon vias, MEMS, Copper, Electrodeposition, Electroplating, Heterogeneous Integration
Sponsors
Sandia National Laboratories
Document Type
Thesis
Language
English
Degree Name
Chemical Engineering
Level of Degree
Masters
Department Name
Chemical and Biological Engineering
First Committee Member (Chair)
Nathan Jackson
Second Committee Member
Lok-Kun Tsui
Third Committee Member
Andrew Hollowell
Recommended Citation
Schmitt, Rebecca P.. "COPPER ELECTRODEPOSITION IN FULL WAFER THICKNESS THROUGH-SILICON VIAS." (2020). https://digitalrepository.unm.edu/cbe_etds/88