Kinematics and Thermodynamics of Nickel(II)-Glycine Complexes Using Carbon Magnetic Resonance

Author

Donald Frederick Shepard

Publication Date

2-23-1979

Abstract

l- ¹³C glycine was studied in nickel(II) solutions using carbon magnetic resonance (CMR). The carboxy bound nickel(II)-glycine complex and the kinetics of complexation between aquated nickel(II) ion and aquated glycine are described. It has been hypothesized that solutions containing no complexation higher than the chelated mono nickel(II)-glycine complex contain five magnetically different glycine species. The effects of these five magnetically different glycine species on the CMR spectra of the nickel(II)-glycine solutions are discussed.

Document Type

Dissertation

Degree Name

Chemistry

Level of Degree

Doctoral

Department Name

Department of Chemistry and Chemical Biology

First Committee Member (Chair)

William M. Litchman

Second Committee Member

William F. Coleman

Third Committee Member

Nicholas A. Matwiyoff

Fourth Committee Member

Robert T Paine Jr.

Recommended Citation

Shepard, Donald Frederick. "Kinematics and Thermodynamics of Nickel(II)-Glycine Complexes Using Carbon Magnetic Resonance." (1979). https://digitalrepository.unm.edu/chem_etds/160