Civil Engineering ETDs

Publication Date

Summer 7-29-2025

Abstract

Mining legacy has led to elevated concentrations of lead (Pb), arsenic (As), and uranium(U) mixtures in waters and soils. Fungi could be used as a bioremediation strategy. However, the role of fungi in these processes is poorly understood. We aim to determine the removal of aqueous Pb and As mixtures by various root fungi species. The fungi Fusarium oxysporum species complex, Darksidea alpha, Edenia sp., Monosporascus sp.1 and Monosporascus sp. 2 were cultivated in aqueous media containing 4 mg/L As and 4 mg/L Pb. Removal of 64.7 to 95.4% Pb and limited As removal (< 12.5%) was measured by inductively coupled plasma optical emission spectroscopy (ICP-OES). Fungi surfaces are negatively charged as determined by zeta potential measurements (range -3.218 to -10.23 mV). Our results indicate that the negative charge of fungi has affinity for cationic species such as Pb and electrostatically repel anionic species like arsenate. Scanning electron microscopy detected Pb on the surface of Monosporascus sp. 1 indicating biosorption of Pb onto the fungi. The results from this work provide insights for the simultaneous removal of metal mixtures, which have relevant implications to inform bioremediation strategies.

Keywords

Root Fungi, Lead Removal, Arsenic Removal, bioremediation

Document Type

Thesis

Language

English

Degree Name

Civil Engineering

Level of Degree

Masters

Department Name

Civil Engineering

First Committee Member (Chair)

Jose Cerrato

Second Committee Member

Anjali Mulchandani

Third Committee Member

Jennifer Rudgers

Fourth Committee Member

Eliane El Hayek

Fifth Committee Member

Donald O. Natvig

Available for download on Thursday, July 29, 2027

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